How is Picric Acid Prepared from Phenol? (NEET Chemistry)

Hint: The compounds made up of carbon and its derivatives are known as organic compounds. Picric acid is also an organic compound having three nitro and a hydroxyl group attached on the benzene ring.

Complete step by step answer:

Picric acid, also known as 2,4,6-trinitrophenol, is an organic compound with a hydroxyl group and three nitro groups attached to a benzene ring. This acidic compound is both reactive and explosive, similar to TNT in terms of explosive power.

Preparation of Picric Acid from Phenol

To prepare picric acid from phenol, phenol undergoes nitration. This process involves reacting phenol with concentrated sulfuric acid and concentrated nitric acid. The sulfuric acid serves as a catalyst and activates the phenol. Then, the nitric acid introduces nitro groups to the benzene ring, specifically targeting the ortho and para positions, which are the most stable sites for these substitutions. The final product is 2,4,6-trinitrophenol, or picric acid.

Reaction Steps:

Step 1: Phenol is treated with concentrated sulfuric acid to form phenol sulfonic acid.

Step 2: This intermediate is then reacted with concentrated nitric acid, leading to the formation of 2,4,6-trinitrophenol (picric acid).

Additional Notes

Picric acid is a toxic compound, soluble in hot water, alcohol, ether, benzene, and acetone. Its high explosive potential makes it suitable for specialized applications, although safety precautions are essential when handling it.